1,Optimization,0
#p opt=(calcfc,ts,noeigentest) freq b3lyp/6-31+g(d) scrf=(solvent=dichloromethane,smd) nosymm empiricaldispersion=gd3
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2,Frequency Calculation,1
#P Geom=AllCheck Guess=TCheck SCRF=Check GenChk RB3LYP/6-31+G(d) Freq
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1,Unidentified,0
#p b3lyp 6-31+g(d) irc=(calcfc,reverse) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm
## Split Here ##
1,Constrained Optimization,0
#p opt=modredundant b3lyp/6-31+g(d) scrf=(solvent=dichloromethane,smd)nosymm empiricaldispersion=gd3
